Matches in SemOpenAlex for { <https://semopenalex.org/work/W2955171014> ?p ?o ?g. }
- W2955171014 endingPage "12562" @default.
- W2955171014 startingPage "12558" @default.
- W2955171014 abstract "Abstract Hydrogen borrowing catalysis serves as a powerful alternative to enolate alkylation, enabling the direct coupling of ketones with unactivated alcohols. However, to date, methods that enable control over the absolute stereochemical outcome of such a process have remained elusive. Here we report a catalytic asymmetric method for the synthesis of enantioenriched cyclohexanes from 1,5‐diols via hydrogen borrowing catalysis. This reaction is mediated by the addition of a chiral iridium(I) complex, which is able to impart high levels of enantioselectivity upon the process. A series of enantioenriched cyclohexanes have been prepared and the mode of enantioinduction has been probed by a combination of experimental and DFT studies." @default.
- W2955171014 created "2019-07-12" @default.
- W2955171014 creator A5020093267 @default.
- W2955171014 creator A5043602702 @default.
- W2955171014 creator A5064282823 @default.
- W2955171014 creator A5080148464 @default.
- W2955171014 creator A5089206379 @default.
- W2955171014 date "2019-08-07" @default.
- W2955171014 modified "2023-10-14" @default.
- W2955171014 title "Catalytic Asymmetric Synthesis of Cyclohexanes by Hydrogen Borrowing Annulations" @default.
- W2955171014 cites W1963936702 @default.
- W2955171014 cites W1970436622 @default.
- W2955171014 cites W1972957600 @default.
- W2955171014 cites W1982545223 @default.
- W2955171014 cites W1988091937 @default.
- W2955171014 cites W2005580699 @default.
- W2955171014 cites W2007585769 @default.
- W2955171014 cites W2011215428 @default.
- W2955171014 cites W2014782813 @default.
- W2955171014 cites W2018014134 @default.
- W2955171014 cites W2038961860 @default.
- W2955171014 cites W2049095005 @default.
- W2955171014 cites W2049232473 @default.
- W2955171014 cites W2051822378 @default.
- W2955171014 cites W2076878887 @default.
- W2955171014 cites W2084386422 @default.
- W2955171014 cites W2092157292 @default.
- W2955171014 cites W2111899059 @default.
- W2955171014 cites W2116672074 @default.
- W2955171014 cites W2129118558 @default.
- W2955171014 cites W2142929429 @default.
- W2955171014 cites W2159906544 @default.
- W2955171014 cites W2171606593 @default.
- W2955171014 cites W2234517106 @default.
- W2955171014 cites W2268262968 @default.
- W2955171014 cites W2313017839 @default.
- W2955171014 cites W2412387777 @default.
- W2955171014 cites W2518500138 @default.
- W2955171014 cites W2552085994 @default.
- W2955171014 cites W2586672300 @default.
- W2955171014 cites W2612673239 @default.
- W2955171014 cites W2623258670 @default.
- W2955171014 cites W2734128104 @default.
- W2955171014 cites W2739439285 @default.
- W2955171014 cites W2744506385 @default.
- W2955171014 cites W2765912000 @default.
- W2955171014 cites W2783137249 @default.
- W2955171014 cites W2807913906 @default.
- W2955171014 cites W2871234943 @default.
- W2955171014 cites W2889822181 @default.
- W2955171014 cites W2949596304 @default.
- W2955171014 cites W2951745006 @default.
- W2955171014 cites W3005470321 @default.
- W2955171014 cites W4205684684 @default.
- W2955171014 cites W4240319713 @default.
- W2955171014 cites W4240612967 @default.
- W2955171014 doi "https://doi.org/10.1002/anie.201907514" @default.
- W2955171014 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6771629" @default.
- W2955171014 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31265208" @default.
- W2955171014 hasPublicationYear "2019" @default.
- W2955171014 type Work @default.
- W2955171014 sameAs 2955171014 @default.
- W2955171014 citedByCount "51" @default.
- W2955171014 countsByYear W29551710142019 @default.
- W2955171014 countsByYear W29551710142020 @default.
- W2955171014 countsByYear W29551710142021 @default.
- W2955171014 countsByYear W29551710142022 @default.
- W2955171014 countsByYear W29551710142023 @default.
- W2955171014 crossrefType "journal-article" @default.
- W2955171014 hasAuthorship W2955171014A5020093267 @default.
- W2955171014 hasAuthorship W2955171014A5043602702 @default.
- W2955171014 hasAuthorship W2955171014A5064282823 @default.
- W2955171014 hasAuthorship W2955171014A5080148464 @default.
- W2955171014 hasAuthorship W2955171014A5089206379 @default.
- W2955171014 hasBestOaLocation W29551710141 @default.
- W2955171014 hasConcept C146686406 @default.
- W2955171014 hasConcept C161790260 @default.
- W2955171014 hasConcept C164361826 @default.
- W2955171014 hasConcept C178790620 @default.
- W2955171014 hasConcept C185592680 @default.
- W2955171014 hasConcept C21951064 @default.
- W2955171014 hasConcept C2910947881 @default.
- W2955171014 hasConcept C512968161 @default.
- W2955171014 hasConceptScore W2955171014C146686406 @default.
- W2955171014 hasConceptScore W2955171014C161790260 @default.
- W2955171014 hasConceptScore W2955171014C164361826 @default.
- W2955171014 hasConceptScore W2955171014C178790620 @default.
- W2955171014 hasConceptScore W2955171014C185592680 @default.
- W2955171014 hasConceptScore W2955171014C21951064 @default.
- W2955171014 hasConceptScore W2955171014C2910947881 @default.
- W2955171014 hasConceptScore W2955171014C512968161 @default.
- W2955171014 hasFunder F4320334627 @default.
- W2955171014 hasIssue "36" @default.
- W2955171014 hasLocation W29551710141 @default.
- W2955171014 hasLocation W29551710142 @default.
- W2955171014 hasLocation W29551710143 @default.
- W2955171014 hasLocation W29551710144 @default.
- W2955171014 hasLocation W29551710145 @default.