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• W2955202783 endingPage "12902" @default.
• W2955202783 startingPage "12898" @default.
• W2955202783 abstract "Abstract A wide range of polyfunctional diaryl‐ and diheteroarylzinc species were prepared in toluene within 10 min to 5 h through an I/Zn or Br/Zn exchange reaction using bimetallic reagents of the general formula R′ 2 Zn⋅2 LiOR (R′= s Bu, t Bu, p Tol). Highly sensitive functional groups, such as a triazine, a ketone, an aldehyde, or a nitro group, were tolerated in these exchange reactions, enabling the synthesis of a plethora of functionalized (hetero)arenes after quenching with various electrophiles. Insight into the constitution and reactivity of these bimetallic mixtures revealed the formation of highly active lithium diorganodialkoxyzincates of type [R′ 2 Zn(OR) 2 Li 2 ]." @default.
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• W2955202783 date "2019-07-19" @default.
• W2955202783 modified "2023-10-10" @default.
• W2955202783 title "Preparation of Polyfunctional Arylzinc Organometallics in Toluene by Halogen/Zinc Exchange Reactions" @default.
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• W2955202783 doi "https://doi.org/10.1002/anie.201906898" @default.
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• W2955202783 hasPublicationYear "2019" @default.
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