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- W2955295619 abstract "Chiral selenium π-acid catalysis has for a long time been lagging behind other areas of asymmetric catalysis due to a lack of highly enantioselective catalysts. In this regard, we recently developed the first chiral selenium π-acid catalyst which performs the oxidative cyclization of β,γ-unsaturated carboxylic acids with high enantioselectivities. We report herein our improved synthesis of this chiral selenium catalyst, which allows access to a large quantity of the catalyst as the diselenide. In addition, the catalyst is tested in the oxidative cyclization of N-methoxy β,γ-unsaturated amides to give iminolactones with high enantioselectivities." @default.
- W2955295619 created "2019-07-12" @default.
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- W2955295619 date "2019-06-28" @default.
- W2955295619 modified "2023-10-02" @default.
- W2955295619 title "Scalable Synthesis of a Chiral Selenium π-Acid Catalyst and Its Use in Enantioselective Iminolactonization of β,γ-Unsaturated Amides" @default.
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- W2955295619 doi "https://doi.org/10.1055/s-0039-1690109" @default.
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