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- W2955321668 endingPage "118979" @default.
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- W2955321668 abstract "The reaction of bis(N-salicylidene)-4,4′-diaminodiphenyl)ether (4OsalH2) with zinc(II) ion affords a 2:2 dinuclear zinc(II) complex formulated as [Zn2(4Osal)2]. A similar 2:2 dinuclear zinc(II) complex, [Zn2(4Ssal)2], can be obtained by the reaction of bis(N-salicylidene)-4,4′-diaminodiphenyl)thioether (4SsalH2) with zinc(II) ion. These two complexes, [Zn2(4Osal)2] and [Zn2(4Ssal)2], take similar helical structures. Although bis(N-salicylidene)-3,3′-diaminodiphenyl)methane (3MsalH2) and bis(N-salicylidene)-2,2′-diaminodiphenyl)thioether (2SsalH2) give dinuclear complexes with similar compositions, [Zn2(3Msal)2] and [Zn2(2Ssal)2], respectively, their structures are quite different from those of [Zn2(4Osal)2] and [Zn2(4Ssal)2]. Namely, [Zn2(3CH2sal)2] and [Zn2(2Ssal)2] take the mosocate and the phenoxo-bridged dinuclear structures, respectively. Such structural differences between the formed complexes occur depending on the relative positions of the two amino groups of the precursor dianiline, and reflect their diffuse reflectance and photoluminescence spectral behaviours. It has become clear that the electronic transitions of such a complex strongly depend on the relative arrangement of the two amino groups in the precursor dianiline compound as well as the kind of the central atom linking two aniline frameworks." @default.
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- W2955321668 date "2019-09-01" @default.
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- W2955321668 title "Syntheses, crystal structures, and solid-state spectroscopic properties of helical and non-helical dinuclear zinc(II) complexes derived from N2O2 ligands with different torsion-generating sources" @default.
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- W2955321668 doi "https://doi.org/10.1016/j.ica.2019.118979" @default.
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