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- W2955449747 abstract "In this paper, the unusual reactivity of the complex Zn(II)-1,4,7-trimethyl-1,4,7-triazacyclononane (2) in the transesterification of the RNA-model substrate, HPNP (3), is reported. The dependence of the reactivity (k2) with pH does not follow the characteristic bell-shape profile typical of complexes with penta-coordinated metal centers. By the contrary, two reactive species, featuring different deprotonation states, are present, with the tri-aqua complex being more reactive than the mono-hydroxy-diaqua one. Apparently, such a difference arises from the total complex charge which plays an important role in the stability of the transition state/s of the reactions. Relevant insight on the reaction mechanism were hence obtained." @default.
- W2955449747 created "2019-07-12" @default.
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- W2955449747 date "2019-07-03" @default.
- W2955449747 modified "2023-09-23" @default.
- W2955449747 title "The Zn(II)-1,4,7-Trimethyl-1,4,7-Triazacyclononane Complex: A Monometallic Catalyst Active in Two Protonation States" @default.
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- W2955449747 doi "https://doi.org/10.3389/fchem.2019.00469" @default.
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