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- W2955728723 abstract "Abstract The reaction of 2-chlorophenylacetic acid with anhydrous copper(II) sulphate in the presence of pyridine resulted in the formation of [Cu 2 (2-ClC 6 H 4 CH 2 COO) 4 (Py) 2 ] ( 1 ). The complex was characterized by FT-IR and X-ray single crystal analysis. The dinuclear copper(II) complex has shown a paddle wheel arrangement with four bridging carboxylate ligands around two copper centers. The axial positions around the paddle wheel copper centers are occupied by pyridine co-ligands. Variable-temperature magnetic susceptibility measurements established strong antiferromagnetic interactions in the complex and the J value between two copper atoms ( J Cu–Cu ) was determined as −147.6 cm −1 . The thermal degradation behavior of the complex was studied in the temperature range 30–1000 °C at different heating rates. The TG curves were subsequently used for the calculations of kinetic and thermodynamic parameters." @default.
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- W2955728723 date "2019-11-01" @default.
- W2955728723 modified "2023-09-28" @default.
- W2955728723 title "A paddle wheel dinuclear Copper(II) carboxylate: Crystal structure, thermokinetic and magnetic properties" @default.
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- W2955728723 doi "https://doi.org/10.1016/j.molstruc.2019.06.095" @default.
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