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- W2955977123 abstract "Abstract Dinuclear phenoxo-bridged nickel complexes [Ni2(L1)H2O(CH3COO)](1) and [Ni2(L2)H2O(CH3COO)](2) (where L1H3° = 2-(2′-hydroxyphenyl)-1,3-bis[4-(2-hydroxyphenyl)-3-azabutenyl]-3-enyl]-1,3-imidazolidine and L2H3° = 2-(3,5-di-tert-butyl-2-hydroxyphenyl)-1,3-bis[4-(3,5-di-tert-butyl-2-hydroxyphenyl)-3-azabutenyl]-1,3-idazolidine, and H stands for dissociable protons) have been synthesized and characterized by different spectroscopic methods. Molecular structure of 2 was determined by X-ray crystallography. Redox properties of complexes 1 and 2 were investigated by cyclic voltammetric studies. As functional mimic of active site of galactose oxidase enzyme, complexes 1 and 2 were utilized for the oxidation of primary alcohol. Both the complexes exhibited catecholase activity. DNA interaction studies on complexes 1 and 2 were also investigated. Self-activated DNA cleavage activity of complex 2 was observed. The cytotoxicity of the complexes 1 and 2 was measured using a standard MTT assay and IC50 values for of 1 and 2 were found to be 21.92 µM and 20.69 µM on MCF-7 breast cancer cell line respectively." @default.
- W2955977123 created "2019-07-12" @default.
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- W2955977123 date "2019-09-01" @default.
- W2955977123 modified "2023-09-24" @default.
- W2955977123 title "The influence of the tertiary butyl group in the ligand frame on the catalytic activities, DNA cleavage ability and cytotoxicity of dinuclear nickel(II) complexes" @default.
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- W2955977123 doi "https://doi.org/10.1016/j.ica.2019.118993" @default.
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