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- W2956008766 endingPage "7050" @default.
- W2956008766 startingPage "7042" @default.
- W2956008766 abstract "Abstract Vanadium oxide (VOx) decorated with gold‐nanoparticles via self‐assembled monolayer approach is herein reported to be an efficient electrocatalyst for both oxygen and hydrogen evolution reactions (OER and HER) in alkali medium. The voids created in the nanoflute of gold‐vanadate were believed to be responsible for high mass transfer allowing the material to be highly applicable as a catalyst for water splitting and nitro‐arene reduction. The nanoflute exhibited high current density with low onset potential value in both OER and HER. The overpotential value at 10 mAcm −2 was observed to be 310 mV with onset potential of 1.43 V in case of OER while the overpotential value for HER was measured to be 282 mV. The nanocatalyst was found to be stable upto 10 h with minimal increment in the overpotential value. The Tafel plot value of 127 mVdec −1 in OER and 131 mVdec −1 in HER also signified for the high efficacy of the catalyst towards splitting of water molecules under high basic condition. The same material was also used as catalyst for reduction of various nitro‐arenes in isopropanol with 0.25 M KOH. The liberation of hydrogen via the oxidation of isopropanol was supposed to be responsible for reduction of nitro‐arenes. The ability of the catalyst to oxidize isopropanol was substantiated from electrochemical studies." @default.
- W2956008766 created "2019-07-12" @default.
- W2956008766 creator A5020299956 @default.
- W2956008766 creator A5028208097 @default.
- W2956008766 creator A5057183079 @default.
- W2956008766 creator A5075207741 @default.
- W2956008766 date "2019-06-24" @default.
- W2956008766 modified "2023-09-26" @default.
- W2956008766 title "Self‐Assembled Monolayer Stabilized Gold‐Vanadate Nanoflute for Water Splitting Reactions" @default.
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