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- W2956029544 abstract "Abstract An oxidative trifunctionalization of aryl alkynoates has been devised via the chalcogenide radical triggered intramolecular 1,4‐aryl migration/decarboxylation cascade to prepare 1,1‐dichalcogenide tetrasubstituted alkenes in high yields (up to 98 %). This operationally simple reaction proceeds under metal‐free conditions, can be executed on gram scale, and highlights formal 1,1‐difunctionalization of alkynes. Synthetic potential of this protocol was demonstrated through a twofold cascade rearrangement to access highly conjugated tetra‐selenylated alkenes along with a cross‐dehydrogenative annulation to prepare fluorene derivative." @default.
- W2956029544 created "2019-07-12" @default.
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- W2956029544 date "2019-07-24" @default.
- W2956029544 modified "2023-10-16" @default.
- W2956029544 title "Atom Transfer Oxidative Radical Cascade of Aryl Alkynoates towards 1,1‐Dichalcogenide Olefins" @default.
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- W2956029544 doi "https://doi.org/10.1002/asia.201900820" @default.
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