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- W2956063313 abstract "A ligand-promoted palladium(II)-catalyzed synthesis of arylalkynes and phthalides from benzoic acids and bromoalkynes via carboxylate-assisted ortho-C–H activation is reported. A series of phthalides with various functional groups are prepared via ortho-alkynylation and alkynylation–annulation. Moreover, the key ortho-alkynylated products are also obtained by controlling the reaction conditions. In addition, heteroaryl acids could react smoothly to form the corresponding alkynylation and cyclization products." @default.
- W2956063313 created "2019-07-12" @default.
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- W2956063313 date "2019-07-02" @default.
- W2956063313 modified "2023-09-26" @default.
- W2956063313 title "Switchable Synthesis of Arylalkynes and Phthalides via Controllable Palladium-Catalyzed Alkynylation and Alkynylation–Annulation of Benzoic Acids with Bromoalkynes" @default.
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- W2956063313 doi "https://doi.org/10.1021/acs.joc.9b01102" @default.
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