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• W2956116087 startingPage "2597" @default.
• W2956116087 abstract "9-Aza-10-boraanthracene stabilized by coordination of an N-heterocyclic carbene was synthesized. The X-ray crystallographic analysis disclosed a planar structure of the 9-aza-10-boraanthracene ring. The theoretical calculation and UV–vis absorption spectrum revealed a narrow HOMO–LUMO gap of 9-aza-10-boraanthracene. In addition, a nucleophilic reactivity of the lone pair of nitrogen atom in 9-aza-10-boraanthrcene was demonstrated by a reaction with MeOTf. The electronic structure of the N-methylated 9-aza-10-boraanthracene cation was also discussed on the basis of X-ray crystallographic analysis and its UV–vis absorption spectrum as well as theoretical calculations." @default.
• W2956116087 created "2019-07-12" @default.
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• W2956116087 date "2019-06-27" @default.
• W2956116087 modified "2023-09-26" @default.
• W2956116087 title "9-Aza-10-boraanthracene Stabilized by Coordination of an N-Heterocyclic Carbene and Its Methylated Cation: Synthesis, Structure, and Electronic Properties" @default.
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• W2956116087 doi "https://doi.org/10.1021/acs.organomet.9b00310" @default.
• W2956116087 hasPublicationYear "2019" @default.
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