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• W2956156922 startingPage "6253" @default.
• W2956156922 abstract "An understanding of the thermodynamic properties of elementary chemical steps of a reaction is important for the development of fundamental reaction theories and for effective industrial practice. In this work, temperature-variable single-molecule fluorescence microscopy was employed to study a reversible redox chemical process and reveal the thermodynamics of chemical elementary reactions at a single-molecule level. Activation energies of pure elementary steps were measured on the level of single molecules and found to be heterogeneously distributed across the population of individual molecules. The activation parameters measured across the population of individual molecules also exhibited a compensation effect and an isokinetic relationship. These results constitute a new single-molecule-level perspective into a chemical reaction." @default.
• W2956156922 created "2019-07-12" @default.
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• W2956156922 date "2019-06-27" @default.
• W2956156922 modified "2023-10-17" @default.
• W2956156922 title "Revealing the Thermodynamic Properties of Elementary Chemical Reactions at the Single-Molecule Level" @default.
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• W2956156922 doi "https://doi.org/10.1021/acs.jpcb.9b03474" @default.
• W2956156922 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31246466" @default.
• W2956156922 hasPublicationYear "2019" @default.
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