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- W2956200217 abstract "A mild and efficient method for the direct difluoromethylenephosphonation of imidazopyridines has been developed using rose bengal (RB) as a photoredox catalyst. Bis(pinacolato)diboron (B2pin2) is found to be a crucial additive in the present reaction. The present methodology is also applicable to other heterocycles like imidazo[2,1-b]thiazole, benzo[d]imidazo-[2,1-b]thiazole, and indole. The reaction possibly proceeds through a single electron transfer (SET) process." @default.
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- W2956200217 date "2019-07-08" @default.
- W2956200217 modified "2023-10-18" @default.
- W2956200217 title "Organophotoredox-Catalyzed C(sp<sup>2</sup>)–H Difluoromethylenephosphonation of Imidazoheterocycles" @default.
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- W2956200217 doi "https://doi.org/10.1021/acs.orglett.9b01954" @default.
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