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- W2956552923 abstract "The present study aimed to model and optimize the dimethyl phthalate (DMP) degradation from aqueous solution using UVC/ Na2S2O8/Fe2+ system based on the response surface methodology (RSM). A high removal efficiency (97%) and TOC reduction (64.2%) were obtained under optimum conditions i.e. contact time = 90 min, SPS concentration = 0.601 mM/L, Fe2+ = 0.075 mM/L, pH = 11 and DMP concentration = 5 mg/L. Quenching experiments confirmed that sulfate radicals were predominant radical species for DMP degradation. The effect of CO3− on DMP degradation was more complicated than other aquatic background anions. The possible pathway for DMP decomposition was proposed according to HPLC and GC–MS analysis. The average oxidation state (AOS) and carbon oxidation state (COS) values as biodegradability indicators demonstrated that the UVC/SPS/Fe2+ system can improve the bioavailability of DMP over the time. Finally, the performance of UVC/SPS/Fe2+ system for DMP treatment in different aquatic solutions: tap water, surface runoff, treated and raw wastewater were found to be 95.7, 88.5, 80.5, and 56.4%, respectively." @default.
- W2956552923 created "2019-07-23" @default.
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- W2956552923 date "2019-07-12" @default.
- W2956552923 modified "2023-10-13" @default.
- W2956552923 title "Degradation of dimethyl phthalate using persulfate activated by UV and ferrous ions: optimizing operational parameters mechanism and pathway" @default.
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- W2956552923 doi "https://doi.org/10.1007/s40201-019-00384-9" @default.
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