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- W2957420733 abstract "Abstract A synthetic method for accessing chiral α‐alkylthio‐α‐alkylmalonates was successfully established. The enantioselective α‐sulfenylation of α‐alkylmalonates via phase‐transfer catalysis [ N ‐alkylthiophthalimide, 50% aq. KOH, toluene, −40 °C and N ‐2′,3′,4′‐trifluorophenyl‐dihydroquinidium bromide] provided the corresponding α‐alkylthio‐α‐alkylmalonates in high chemical yields (up to 97%) and optical purities (up to 90% ee )." @default.
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- W2957420733 date "2019-08-21" @default.
- W2957420733 modified "2023-10-16" @default.
- W2957420733 title "Enantioselective Synthesis of Chiral α‐Alkylthiomalonates via a Phase‐Transfer‐Catalyzed α‐Sulfenylation of α‐Alkylmalonates" @default.
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- W2957420733 doi "https://doi.org/10.1002/ajoc.201900346" @default.
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