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- W2957487718 abstract "Abstract High surface area (2022 m2.g−1) activated carbon (CSZ-C) is prepared by single step thermochemical activation of agro-waste lignocellulosic biomass. The turbostratic structure of CSZ-C enriched with microporosity promises the potential for adsorptive removal of organic dyes and active pharmaceutical ingredients. The π-π interaction between aromatic rings of organic pollutants and discrete graphitic clusters/units of CSZ-C facilitates the adsorption. The electrostatic interactions, hydrogen bonding, trapping of organic pollutants by structural defects, etc. also play the roles and their contributions are governed by charge, chemical structure and molecular size of organic pollutants. The CSZ-C exhibited faster and higher adsorption of cationic dyes (523–537 mg.g−1) than the anionic dye (434.8 mg.g−1), whereas neutral organic pollutant tetracycline showed comparatively slower adsorption. Nevertheless, CSZ-C revealed significantly higher adsorption (595.2 mg.g−1) of tetracycline, which is governed by hydrogen bonding besides the π-π interaction between the oxygen functionalities-enriched tetracycline and the CSZ-C. The continuous flow separative unit having a fixed bed of CSZ-C efficiently removed the organic dyes from the industrial wastewater. Furthermore, the partition coefficients and breakthrough curves suggest the fast and high adsorptive removal efficiency of CSZ-C activated carbon for organic dyes." @default.
- W2957487718 created "2019-07-23" @default.
- W2957487718 creator A5059458608 @default.
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- W2957487718 date "2019-12-01" @default.
- W2957487718 modified "2023-10-17" @default.
- W2957487718 title "Fast and efficient adsorptive removal of organic dyes and active pharmaceutical ingredient by microporous carbon: Effect of molecular size and charge" @default.
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- W2957487718 doi "https://doi.org/10.1016/j.cej.2019.122218" @default.
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