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- W2957762600 abstract "The interaction between gold sub-nanometer clusters composed of ten atoms (Au10) and tetrakis(4-sulfonatophenyl)porphyrin (TPPS) was investigated through various spectroscopic techniques. Under mild acidic conditions, the formation, in aqueous solutions, of nanohybrid assemblies of porphyrin J-aggregates and Au10 cluster nanoparticles was observed. This supramolecular system tends to spontaneously cover glass substrates with a co-deposit of gold nanoclusters and porphyrin nanoaggregates, which exhibit circular dichroism (CD) spectra reflecting the enantiomorphism of histidine used as capping and reducing agent. The morphology of nanohybrid assemblies onto a glass surface was revealed by atomic force microscopy (AFM), and showed the concomitant presence of gold nanoparticles with an average size of 130 nm and porphyrin J-aggregates with lengths spanning from 100 to 1000 nm. Surface-enhanced Raman scattering (SERS) was observed for the nanohybrid assemblies." @default.
- W2957762600 created "2019-07-23" @default.
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- W2957762600 date "2019-07-18" @default.
- W2957762600 modified "2023-10-08" @default.
- W2957762600 title "Nanohybrid Assemblies of Porphyrin and Au10 Cluster Nanoparticles" @default.
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- W2957762600 doi "https://doi.org/10.3390/nano9071026" @default.
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