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- W2959402849 abstract "In the present study, the hydrogen storage performance of multi-principal-component ZrTiVNiCrFe alloy produced through rapid solidification has been examined by electrochemical methods and gas-solid reactions. XRD and EBSD analyses reveal the hexagonal Laves phase structure (type C14) with average grain size of 300 nm and root-mean-square microstrain of 0.19%. Cyclic voltammetry and electrochemical impedance spectroscopy analyses in the hydrogen sorption/desorption region give insight to the sorption/desorption kinetics and the change in the desorption charge in terms of the applied potential. The pressure-composition isotherms measured in course of gas-solid reaction confirm the hydrogen storage capacity reaching 1.6 wt% at the first hydrogenation at room temperature, then reducing to 1.3–1.4% during subsequent cycling. According to the calorimetric titration study, there is a significant hysteresis primarily caused by the non-equilibrium character of the hydrogenation process." @default.
- W2959402849 created "2019-07-23" @default.
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- W2959402849 date "2020-02-01" @default.
- W2959402849 modified "2023-10-06" @default.
- W2959402849 title "Evaluation of hydrogen storage performance of ZrTiVNiCrFe in electrochemical and gas-solid reactions" @default.
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- W2959402849 doi "https://doi.org/10.1016/j.ijhydene.2019.06.157" @default.
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