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- W2959654016 abstract "Abstract We report the anion [Al(NON Ar )(Se)] − (NON Ar =[O(SiMe 2 NAr) 2 ] 2− , Ar=2,6‐ i Pr 2 C 6 H 3 ), which is an isoelectronic Group 13 metal analogue of the carbonyl group containing an aluminium–selenium multiple bond. It was synthesized in a single step from the reaction of the aluminyl anion [Al(NON Ar )] − with elemental selenium. Spectroscopic, crystallographic, and computational analysis confirmed multiple bonding between aluminium and selenium. Addition of a second equivalent of selenium afforded the diselenirane, [Al(NON Ar )(κ 2 ‐Se 2 )] − , which is an isoelectronic analogue of the dioxirane group." @default.
- W2959654016 created "2019-07-23" @default.
- W2959654016 creator A5022940323 @default.
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- W2959654016 date "2019-08-13" @default.
- W2959654016 modified "2023-10-03" @default.
- W2959654016 title "Isoelectronic Aluminium Analogues of Carbonyl and Dioxirane Moieties" @default.
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- W2959654016 doi "https://doi.org/10.1002/anie.201907884" @default.
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