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• W2959654480 abstract "Organometallic nanostructures are promising candidates for applications in optoelectronics, magnetism and catalysis. Our bottom-up approach employs a cyano-functionalized terminal alkyne species (CN-DETP) on the Ag(110) surface to fabricate 2D domains of regularly stacked Ag-acetylide nanowires. We unravel their adsorption properties and give evidence to their organometallic character with the aid of complementary surface-sensitive techniques, i.e. scanning tunneling microscopy, X-ray photoelectron spectroscopy and near-edge X-ray absorption fine-structure spectroscopy. Guided by the anisotropic (110) surface, highly oriented nanowires form in two enantiomorphic domains of regularly stacked trans isomers, whereby the bifunctional design of CN-DETP gives rise to orthogonal bonding motifs. Based on STM imaging, we find high thermal stability of the Ag-bis-acetylide wires, without conversion into graphdiyne chains. Our approach based on orthogonal bifunctionalization and selective functional group recognition extends the toolbox of creating alkyne-based nanostructures at interfaces." @default.
• W2959654480 created "2019-07-23" @default.
• W2959654480 creator A5000630517 @default.
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• W2959654480 date "2019-07-13" @default.
• W2959654480 modified "2023-09-27" @default.
• W2959654480 title "Cyano-functionalized Ag-bis-acetylide wires on Ag(110)" @default.
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• W2959654480 hasPublicationYear "2019" @default.
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