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- W2959893501 abstract "Abstract The mobilities and activities of ions in NaCl-glucose-water mixtures are probed by means of conductometry and potentiometry. A positive deviation of the limiting conductance from the Stokes-Einstein (SE) relation is observed. This striking effect is discussed in terms of ‘excluded volume’ concept for strongly heterogeneous liquids. A drastic difference between sodium cations and chloride anions is argued resting on measurements with ion selective electrodes. The microscopic structure of water-glucose solutions is thoroughly addressed by classical molecular dynamics (MD) method. The MD simulations reproduce qualitatively the main experimental findings; trends in the behavior of the Na+ and Cl− ions are attributed to a noticeable difference in the structure and dynamics of their solvation shells." @default.
- W2959893501 created "2019-07-23" @default.
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- W2959893501 date "2019-10-01" @default.
- W2959893501 modified "2023-09-27" @default.
- W2959893501 title "Electrolyte in heterogeneous water-glucose mixtures: A view from experiment and molecular modeling" @default.
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- W2959893501 doi "https://doi.org/10.1016/j.chemphys.2019.110440" @default.
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