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• W2959958838 endingPage "117346" @default.
• W2959958838 startingPage "117346" @default.
• W2959958838 abstract "The photophysics and structural transition dynamics of a bio-active flavin lumichrome (LM) entrapped in two sugars based neutral surfactants were reported. Sugar-based surfactants, which were used for research purpose are potential environmentally friendly, green alternative amphiphilic surface active substance compared to other kinds of common surfactants. Here, two alkyl glucoside surfactants n-octyl-β-D-glucopyranoside (OBG) and n-octyl-β-D-thioglucopyranoside (OBTG) were used. This work is carried out by using steady-state absorption and fluorescence emission spectroscopy along with time-resolved fluorescence emission techniques. Photophysics of LM was modulated several folds in these two sugar-based neutral micelles. LM exhibits excitation and emission wavelength dependent fluorescence properties in these two sugars based neutral micelles. LM confined in the micellar environments exhibited structural transition dynamism, i.e. different kinds of conformers are equilibrated. Herein, different conformers of LM are identified and explained with the help of spectroscopic methods. From the fluorescence anisotropy measurement, it was found that the rotational relaxation time of LM in OBG micelle was more compared to that in OBTG micelle, which indicates that the LM molecule faced much more constrained environment in OBG micellar media." @default.
• W2959958838 created "2019-07-23" @default.
• W2959958838 creator A5010451738 @default.
• W2959958838 creator A5012579792 @default.
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• W2959958838 date "2020-01-01" @default.
• W2959958838 modified "2023-09-30" @default.
• W2959958838 title "Structural transition dynamics of biologically active flavins in alkylglucoside surfactants aggregates" @default.
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• W2959958838 doi "https://doi.org/10.1016/j.saa.2019.117346" @default.
• W2959958838 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31344577" @default.
• W2959958838 hasPublicationYear "2020" @default.
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