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- W2960391446 abstract "The phenomenological model of nikel-iron spinel nucleation with spinel structure based on the partial charge theory and analysis of hydrolysis and polycondensation processes at the interaction of Fe3+-, Fe2+- and Ni2+- hydroxocomplexes at different pH values of reaction medium was proposed. UV-vis optical spectroscopy was used for verification of the obtained results about the regularities of hydroxocomplexes formation. Crystal quasichemistry approach was applied for nucleation of nikel-iron spinel under the conditions of predomination of different defect types in NixFe3-xO4-δ (δ is oxygen non-stoichiometry) spinel lattice. The analysis of changes in electrical conductivity and lattice parameter of defect nickel-iron spinel as a function of Ni2+ atomic concentration was done for different values of d parameter." @default.
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- W2960391446 date "2019-07-10" @default.
- W2960391446 modified "2023-10-17" @default.
- W2960391446 title "The Mechanisms of Nickel-Iron Spinel Phase Nucleation in Aquous Solutions: Crystal Quasichemical Approach" @default.
- W2960391446 doi "https://doi.org/10.15330/pcss.20.2.156-164" @default.
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