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- W296143932 abstract "Publisher Summary This chapter discusses the chemistry and stereochemistry of polymerization and copolymerization reactions with transition metal catalysts. The most prominent feature of many transition metal catalysts is their ability to produce stereoregular polymers of 1-alkenes. This feature adds a new dimension to the characterization of transition metal catalysts, the analysis of catalyst features, and polymerization parameters influencing the type and the level of polymer stereoregularity. In general, polymer stereoregularity can be defined as the existence of a certain order in the spatial structure of a polymer chain. The order is determined by two circumstances. First, during the polymer synthesis the monomer units are linked with each other in a certain regular manner, which depends on the structure of active centers. This regularity becomes ‘‘frozen’’ during the polymer chain formation and it cannot be later altered or changed, except for some rear cases of post-polymerization epimerization reactions (usually radical or cationic reactions). This aspect of polymer stereoregularity is one of the principal subjects of this chapter Second, regularly linked polymer chains spontaneously arrange themselves into particular helical forms. These helical structures easily form three-dimensional regular agglomerates, polymer crystals." @default.
- W296143932 created "2016-06-24" @default.
- W296143932 creator A5085740298 @default.
- W296143932 date "2007-01-01" @default.
- W296143932 modified "2023-09-26" @default.
- W296143932 title "Chapter 3 Chemistry and Stereochemistry of Polymerization and Copolymerization Reactions with Transition Metal Catalysts" @default.
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