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- W2961830652 abstract "The alternating copolymer based on poly (ether ether ketone) (PEEK) is synthesized with ordered side chain. A series of novel anion exchange membranes grafte with the 1, 2-dimethylimidazole and 1-vinylimidazole are obtained. The copolymer was verified by 1H NMR and the crosslinked membranes are further investigated by solvability test. The ordered hydrophilic side chains form well-defined microphase separation structure, which are proved by Transmission electron micrographs microscopy (TEM). The ionic conductivity is 0.075 S/cm at 80 °C of Im-PEEK-0 uncross-linked membrane. With the addition of 1-vinylimidazole, the maximum stress increases to 66.57 MPa, the water uptake drop to 17.1% and swelling ratio drop to 14.8% at 80 °C of Im-PEEK-0.3 membrane. The hydroxide conductivity remains 82.8% in 2 mol L−1 NaOH solution at 60 °C for 400 h. Meanwhile, all the membranes exhibit excellent thermal stability. Overall, the ordered imidazolium-functionalized side chains provide a method to balance hydroxide conductivity and alkali stability of anion exchange membranes." @default.
- W2961830652 created "2019-07-23" @default.
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- W2961830652 date "2019-08-01" @default.
- W2961830652 modified "2023-10-15" @default.
- W2961830652 title "Improved conductivity and stability of anion exchange membranes by introducing steric hindrance and crosslinked structure" @default.
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- W2961830652 doi "https://doi.org/10.1016/j.ijhydene.2019.06.121" @default.
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