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- W2962355112 endingPage "107479" @default.
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- W2962355112 abstract "Two new luminescent metal–organic coordination polymers (MOCPs) of {[Zn6(L)2(H2O)7]·(DMF)2}n (1) and {[Zn(H4L)(bpy)0.5(H2O)2]·H2O}n (2) were solvothermally constructed using zinc salts and ligands (H6L = 5,5′-(propane-2,2-diyl)bis(2-hydroxyisophthalic acid), bpy = 4,4′-bipyridine). The resulted MOCPs were characterized by elemental analysis, powder X-ray diffraction, and single-crystal X-ray diffraction. Single-crystal X-ray study results reveal that compounds 1 and 2 belong to P 1¯ and P 21/n space group and show a two- and one-dimensional structure, respectively. Their photoluminescence (PL) properties and thermal properties were also studied. Interestingly, the luminescent responses of compounds 1 and 2 show highly sensitive detection of Fe3+ via an obvious fluorescence quenching. The detection limits of compounds 1 and 2 are 0.25 μM and 0.19 μM toward Fe3+. Compound 2 possesses a ring structure, which is big enough to allow small molecules to easily move into the crystal skeleton and interact with each other. Thus, the luminescence responses of compound 2 were investigated for various organic solvents. These results show that compound 2 has great potential to be developed as the favorable sensor for highly selective detection of nitrobenzene." @default.
- W2962355112 created "2019-07-23" @default.
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- W2962355112 date "2019-09-01" @default.
- W2962355112 modified "2023-10-18" @default.
- W2962355112 title "Two bifunctional photoluminescent Zn (II) coordination polymers for detection of Fe3+ ion and nitrobenzene" @default.
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- W2962355112 doi "https://doi.org/10.1016/j.inoche.2019.107479" @default.
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