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- W2962880787 abstract "The authors explored the thermal decomposition characteristics of perfluoroisobutyronitrile–carbon dioxide (C 4F 7N–CO 2) gas mixture as eco-friendly dielectric medium. The main by-products and decomposition mechanism of C 4F 7N–CO 2 gas mixture under different temperature and gas pressure conditions were revealed and analysed. It was found that the thermal decomposition of 6%C 4F 7N–94%CO 2 gas mixture starts at about 350°C (0.15 MPa), producing C 3F 6 and CO first. Some other characteristic by-products such as CF 4, C 2F 6, CF 3CN, COF 2 and (CN) 2 could also be detected at higher temperature. The yield of C 3F 6, (CN) 2 increased with the temperature (lower than 450°C) first and then decreased when it reached to 500°C. While the yield of CO, C 3F 8, COF 2 and CF 3CN increased with temperature (350–550°C). The generation of CF 4 and C 2F 6 begins at temperatures higher than 500°C, which can be used as the feature component of severe overheating fault. The thermal decomposition amount and by-products yield of C 4F 7N–CO 2 gas mixture slowed down with the increase of gas pressure, indicating that C 4F 7N–CO 2 gas mixture is quite suitable used at high-pressure equipment, especially high-voltage devices such as gas insulated switchgear." @default.
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- W2962880787 date "2020-02-01" @default.
- W2962880787 modified "2023-10-14" @default.
- W2962880787 title "Study on the thermal decomposition characteristics of C <sub>4</sub> F <sub>7</sub> N–CO <sub>2</sub> mixture as eco‐friendly gas‐insulating medium" @default.
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- W2962880787 doi "https://doi.org/10.1049/hve.2019.0032" @default.
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