Matches in SemOpenAlex for { <https://semopenalex.org/work/W2962907138> ?p ?o ?g. }
- W2962907138 endingPage "93" @default.
- W2962907138 startingPage "93" @default.
- W2962907138 abstract "Borohydride ligands featuring multiple pendant donor functionalities have been prevalent in the chemical literature for many decades now. More recent times has seen their development into new families of so-called soft scorpionates, for example, those featuring sulfur based donors. Despite all of these developments, those ligands containing just one pendant group are rare. This article explores one ligand family based on the 2-mercaptopyridine heterocycle. The coordination chemistry of the monosubstituted ligand, [H3B(mp)]− (mp = 2-mercaptopyridyl), has been explored. Reaction of Na[BH3(mp)] with one equivalent of Cu(I)Cl in the presence of either triphenylphosphine or tricyclohexylphosphine co-ligands leads to the formation of [Cu{H3B(mp)}(PR3)] (R = Ph, 1; Cy, 2), respectively. Structural characterization confirms a κ3-S,H,H coordination mode for the borohydride-based ligand within 1 and 2, involving a dihydroborate bridging interaction (BH2Cu) with the copper centers." @default.
- W2962907138 created "2019-07-30" @default.
- W2962907138 creator A5014634951 @default.
- W2962907138 creator A5032348204 @default.
- W2962907138 creator A5038013597 @default.
- W2962907138 creator A5041015784 @default.
- W2962907138 creator A5042557567 @default.
- W2962907138 date "2019-07-24" @default.
- W2962907138 modified "2023-09-23" @default.
- W2962907138 title "Adding to the Family of Copper Complexes Featuring Borohydride Ligands Based on 2-Mercaptopyridyl Units" @default.
- W2962907138 cites W1956827695 @default.
- W2962907138 cites W1969360633 @default.
- W2962907138 cites W1985548752 @default.
- W2962907138 cites W1991840782 @default.
- W2962907138 cites W1995514696 @default.
- W2962907138 cites W2004001409 @default.
- W2962907138 cites W2009236200 @default.
- W2962907138 cites W2030411380 @default.
- W2962907138 cites W2032304951 @default.
- W2962907138 cites W2037927520 @default.
- W2962907138 cites W2043038192 @default.
- W2962907138 cites W2044366970 @default.
- W2962907138 cites W2054018358 @default.
- W2962907138 cites W2059205366 @default.
- W2962907138 cites W2065562483 @default.
- W2962907138 cites W2065684984 @default.
- W2962907138 cites W2070513934 @default.
- W2962907138 cites W2085243838 @default.
- W2962907138 cites W2089901760 @default.
- W2962907138 cites W2092847093 @default.
- W2962907138 cites W2102110758 @default.
- W2962907138 cites W2125123611 @default.
- W2962907138 cites W2132454074 @default.
- W2962907138 cites W2160647578 @default.
- W2962907138 cites W2165502376 @default.
- W2962907138 cites W2170365874 @default.
- W2962907138 cites W2179476654 @default.
- W2962907138 cites W2180002404 @default.
- W2962907138 cites W2322924255 @default.
- W2962907138 cites W2332197269 @default.
- W2962907138 cites W2335276209 @default.
- W2962907138 cites W2341306918 @default.
- W2962907138 cites W2343892816 @default.
- W2962907138 cites W2493622656 @default.
- W2962907138 cites W2517655170 @default.
- W2962907138 cites W2573987401 @default.
- W2962907138 cites W2602791658 @default.
- W2962907138 cites W2771135989 @default.
- W2962907138 cites W2783915718 @default.
- W2962907138 cites W2811418726 @default.
- W2962907138 cites W2883709245 @default.
- W2962907138 cites W2902268813 @default.
- W2962907138 cites W2908341082 @default.
- W2962907138 cites W2911867752 @default.
- W2962907138 cites W2912706776 @default.
- W2962907138 cites W2916579451 @default.
- W2962907138 cites W2944538985 @default.
- W2962907138 cites W2949895871 @default.
- W2962907138 cites W2950409873 @default.
- W2962907138 cites W4213322344 @default.
- W2962907138 cites W4239299913 @default.
- W2962907138 doi "https://doi.org/10.3390/inorganics7080093" @default.
- W2962907138 hasPublicationYear "2019" @default.
- W2962907138 type Work @default.
- W2962907138 sameAs 2962907138 @default.
- W2962907138 citedByCount "1" @default.
- W2962907138 countsByYear W29629071382022 @default.
- W2962907138 crossrefType "journal-article" @default.
- W2962907138 hasAuthorship W2962907138A5014634951 @default.
- W2962907138 hasAuthorship W2962907138A5032348204 @default.
- W2962907138 hasAuthorship W2962907138A5038013597 @default.
- W2962907138 hasAuthorship W2962907138A5041015784 @default.
- W2962907138 hasAuthorship W2962907138A5042557567 @default.
- W2962907138 hasBestOaLocation W29629071381 @default.
- W2962907138 hasConcept C115624301 @default.
- W2962907138 hasConcept C116569031 @default.
- W2962907138 hasConcept C155647269 @default.
- W2962907138 hasConcept C161790260 @default.
- W2962907138 hasConcept C170493617 @default.
- W2962907138 hasConcept C178790620 @default.
- W2962907138 hasConcept C185592680 @default.
- W2962907138 hasConcept C188027245 @default.
- W2962907138 hasConcept C21951064 @default.
- W2962907138 hasConcept C2777247709 @default.
- W2962907138 hasConcept C2778931688 @default.
- W2962907138 hasConcept C544153396 @default.
- W2962907138 hasConcept C544778455 @default.
- W2962907138 hasConcept C55352516 @default.
- W2962907138 hasConcept C55493867 @default.
- W2962907138 hasConcept C68913812 @default.
- W2962907138 hasConcept C71240020 @default.
- W2962907138 hasConcept C8010536 @default.
- W2962907138 hasConceptScore W2962907138C115624301 @default.
- W2962907138 hasConceptScore W2962907138C116569031 @default.
- W2962907138 hasConceptScore W2962907138C155647269 @default.
- W2962907138 hasConceptScore W2962907138C161790260 @default.
- W2962907138 hasConceptScore W2962907138C170493617 @default.
- W2962907138 hasConceptScore W2962907138C178790620 @default.