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- W2962917872 abstract "Abstract Structural modularity of polymer frameworks is a key advantage of covalent organic polymers, however, only C, N, O, Si, and S have found their way into their building blocks so far. Here, the toolbox available to polymer and materials chemists is expanded by one additional nonmetal, phosphorus. Starting with a building block that contains a λ 5 ‐phosphinine (C 5 P) moiety, a number of polymerization protocols are evaluated, finally obtaining a π‐conjugated, covalent phosphinine‐based framework (CPF‐1) through Suzuki–Miyaura coupling. CPF‐1 is a weakly porous polymer glass (72.4 m 2 g −1 BET at 77 K) with green fluorescence ( λ max =546 nm) and extremely high thermal stability. The polymer catalyzes hydrogen evolution from water under UV and visible light irradiation without the need for additional co‐catalyst at a rate of 33.3 μmol h −1 g −1 . These results demonstrate for the first time the incorporation of the phosphinine motif into a complex polymer framework. Phosphinine‐based frameworks show promising electronic and optical properties, which might spark future interest in their applications in light‐emitting devices and heterogeneous catalysis." @default.
- W2962917872 created "2019-07-30" @default.
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- W2962917872 date "2019-08-13" @default.
- W2962917872 modified "2023-10-15" @default.
- W2962917872 title "A π‐Conjugated, Covalent Phosphinine Framework" @default.
- W2962917872 cites W14083661 @default.
- W2962917872 cites W1885794747 @default.
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- W2962917872 cites W1995465457 @default.
- W2962917872 cites W2000828198 @default.
- W2962917872 cites W2004865495 @default.
- W2962917872 cites W2006670790 @default.
- W2962917872 cites W2010598559 @default.
- W2962917872 cites W2012055701 @default.
- W2962917872 cites W2017873440 @default.
- W2962917872 cites W2043939855 @default.
- W2962917872 cites W2048575095 @default.
- W2962917872 cites W2054406083 @default.
- W2962917872 cites W2064158892 @default.
- W2962917872 cites W2067658025 @default.
- W2962917872 cites W2069857345 @default.
- W2962917872 cites W2074211433 @default.
- W2962917872 cites W2078771835 @default.
- W2962917872 cites W2080344382 @default.
- W2962917872 cites W2090045000 @default.
- W2962917872 cites W2092153004 @default.
- W2962917872 cites W2093102355 @default.
- W2962917872 cites W2111118274 @default.
- W2962917872 cites W2127362235 @default.
- W2962917872 cites W2130849112 @default.
- W2962917872 cites W2136154971 @default.
- W2962917872 cites W2147257319 @default.
- W2962917872 cites W2147834907 @default.
- W2962917872 cites W2148028358 @default.
- W2962917872 cites W2148729236 @default.
- W2962917872 cites W2149165785 @default.
- W2962917872 cites W2152356859 @default.
- W2962917872 cites W2158233227 @default.
- W2962917872 cites W2159077114 @default.
- W2962917872 cites W2161795644 @default.
- W2962917872 cites W2163162657 @default.
- W2962917872 cites W2167999470 @default.
- W2962917872 cites W2168761500 @default.
- W2962917872 cites W2170695566 @default.
- W2962917872 cites W2170714139 @default.
- W2962917872 cites W2197459467 @default.
- W2962917872 cites W2218002557 @default.
- W2962917872 cites W2252397296 @default.
- W2962917872 cites W2253492139 @default.
- W2962917872 cites W2275052379 @default.
- W2962917872 cites W2293950749 @default.
- W2962917872 cites W2301189567 @default.
- W2962917872 cites W2324964879 @default.
- W2962917872 cites W2339138432 @default.
- W2962917872 cites W2412037904 @default.
- W2962917872 cites W2442970291 @default.
- W2962917872 cites W2469904254 @default.
- W2962917872 cites W2522247135 @default.
- W2962917872 cites W2559781199 @default.
- W2962917872 cites W2595019347 @default.
- W2962917872 cites W2610537659 @default.
- W2962917872 cites W2734568722 @default.
- W2962917872 cites W2737003329 @default.
- W2962917872 cites W2743381581 @default.
- W2962917872 cites W2750235251 @default.
- W2962917872 cites W2752146848 @default.
- W2962917872 cites W2764139560 @default.
- W2962917872 cites W2765976161 @default.
- W2962917872 cites W2793862433 @default.
- W2962917872 cites W2884764817 @default.
- W2962917872 cites W2889186339 @default.
- W2962917872 cites W2949370038 @default.
- W2962917872 cites W2950460964 @default.
- W2962917872 cites W4230465461 @default.
- W2962917872 cites W4231957253 @default.
- W2962917872 cites W4233760750 @default.
- W2962917872 cites W4241923101 @default.
- W2962917872 cites W4246035912 @default.
- W2962917872 cites W4247940223 @default.
- W2962917872 cites W4253573602 @default.
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- W2962917872 doi "https://doi.org/10.1002/chem.201900281" @default.
- W2962917872 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6790668" @default.
- W2962917872 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31322767" @default.
- W2962917872 hasPublicationYear "2019" @default.
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