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• W2962964148 abstract "Abstract The iron arsenide Eu 3 Fe 2 O 5 Fe 2 As 2 was synthesized at 1173–1373 K in a resistance furnace and characterized by X-ray powder diffraction with Rietveld analysis: Sr 3 Fe 2 O 5 Cu 2 S 2 type, I 4/ mmm , a = 406.40(1) pm, c = 2646.9(1) pm. Layers of edge-sharing FeAs 4/4 tetrahedra are separated by perovskite-like oxide blocks. No structural transition occurs in the temperature range from 10 to 300 K. Magnetic measurements have revealed Curie–Weiss behavior with an effective magnetic moment of 7.79 μ B per europium atom in agreement with the theoretical value of 7.94 μ B for Eu 2+ . A drop in the magnetic susceptibility at 5 K indicates possible antiferromagnetic ordering. 151 Eu and 57 Fe Mössbauer spectroscopic measurements have confirmed a beginning cooperative magnetic phenomenon by showing significantly broadened spectra at 4.8 K compared to those at 78 K." @default.
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• W2962964148 date "2015-06-23" @default.
• W2962964148 modified "2023-09-23" @default.
• W2962964148 title "Synthesis, crystal structure and magnetism of Eu₃Sc₂O₅Fe₂As₂" @default.
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• W2962964148 doi "https://doi.org/10.1515/znb-2015-0087" @default.
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