FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2962964955> ?p ?o ?g. }

• W2962964955 endingPage "10332" @default.
• W2962964955 startingPage "10323" @default.
• W2962964955 abstract "A convenient synthetic route to Ga-stabilized pnictogen-centered radicals and gallapnictenes by manipulation of pnictogen–carbon bond strengths is presented. Two equivalents of LGa (L = HC[C(Me)N(Dip)]2, Dip = 2,6-i-Pr2C6H3) react with CpArAsCl2 (CpAr = C5(4-t-BuC6H4)5) with formation of the arsenic-centered radical [L(Cl)Ga]2As·1. In contrast, the analogous reaction with TerSbCl2 (Ter = 2,6-Mes2C6H3; Mes = 2,4,6-Me3C6H2) yields the gallastibene LGa═SbTer (2) containing a Ga–Sb double bond, whereas reactions of DipSbCl2 with one and two equivalents of LGa give the monoinsertion and bisinsertion products L(Cl)GaSb(ClDip) (3) and [L(Cl]Ga]2SbDip (4), respectively. 1–4 were structurally characterized by single crystal X-ray diffraction. The description of 1 as an arsenic-centered radical is consistent with results of electron paramagnetic resonance and density functional theory (DFT) studies. The π-bonding in LGa═SbTer (2) is estimated to 10.68 kcal mol–1 by variable-temperature (VT) NMR spectroscopy, and DFT studies reveal a significant π-bonding interaction between Sb and Ga." @default.
• W2962964955 created "2019-07-30" @default.
• W2962964955 creator A5000200671 @default.
• W2962964955 creator A5004351252 @default.
• W2962964955 creator A5026791744 @default.
• W2962964955 creator A5029514013 @default.
• W2962964955 creator A5075599271 @default.
• W2962964955 date "2019-07-23" @default.
• W2962964955 modified "2023-10-16" @default.
• W2962964955 title "Synthesis of a Ga-Stabilized As-Centered Radical and a Gallastibene by Tailoring Group 15 Element–Carbon Bond Strengths" @default.
• W2962964955 cites W1969957955 @default.
• W2962964955 cites W1971080513 @default.
• W2962964955 cites W1979746302 @default.
• W2962964955 cites W1982567581 @default.
• W2962964955 cites W2017374505 @default.
• W2962964955 cites W2031258267 @default.
• W2962964955 cites W2032842297 @default.
• W2962964955 cites W2042061343 @default.
• W2962964955 cites W2073583679 @default.
• W2962964955 cites W2082911375 @default.
• W2962964955 cites W2097459663 @default.
• W2962964955 cites W2099037802 @default.
• W2962964955 cites W2103159155 @default.
• W2962964955 cites W2112455205 @default.
• W2962964955 cites W2116659247 @default.
• W2962964955 cites W2122005358 @default.
• W2962964955 cites W2123469142 @default.
• W2962964955 cites W2125332145 @default.
• W2962964955 cites W2133693383 @default.
• W2962964955 cites W2146051607 @default.
• W2962964955 cites W2168542043 @default.
• W2962964955 cites W2169432568 @default.
• W2962964955 cites W2313962251 @default.
• W2962964955 cites W2314303973 @default.
• W2962964955 cites W2314410092 @default.
• W2962964955 cites W2323940841 @default.
• W2962964955 cites W2325950078 @default.
• W2962964955 cites W2328097957 @default.
• W2962964955 cites W2402131645 @default.
• W2962964955 cites W2508610940 @default.
• W2962964955 cites W2515021821 @default.
• W2962964955 cites W2549496238 @default.
• W2962964955 cites W2560444515 @default.
• W2962964955 cites W2578303176 @default.
• W2962964955 cites W2604156473 @default.
• W2962964955 cites W2605049812 @default.
• W2962964955 cites W2765341578 @default.
• W2962964955 cites W2777397081 @default.
• W2962964955 cites W2781584819 @default.
• W2962964955 cites W2783189149 @default.
• W2962964955 cites W2790262540 @default.
• W2962964955 cites W2791185155 @default.
• W2962964955 cites W2799557896 @default.
• W2962964955 cites W2811256018 @default.
• W2962964955 cites W2895287345 @default.
• W2962964955 cites W2908625111 @default.
• W2962964955 cites W2915729336 @default.
• W2962964955 cites W2946716551 @default.
• W2962964955 cites W30834980 @default.
• W2962964955 cites W4210962488 @default.
• W2962964955 doi "https://doi.org/10.1021/acs.inorgchem.9b01519" @default.
• W2962964955 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31335127" @default.
• W2962964955 hasPublicationYear "2019" @default.
• W2962964955 type Work @default.
• W2962964955 sameAs 2962964955 @default.
• W2962964955 citedByCount "44" @default.
• W2962964955 countsByYear W29629649552019 @default.
• W2962964955 countsByYear W29629649552020 @default.
• W2962964955 countsByYear W29629649552021 @default.
• W2962964955 countsByYear W29629649552022 @default.
• W2962964955 countsByYear W29629649552023 @default.
• W2962964955 crossrefType "journal-article" @default.
• W2962964955 hasAuthorship W2962964955A5000200671 @default.
• W2962964955 hasAuthorship W2962964955A5004351252 @default.
• W2962964955 hasAuthorship W2962964955A5026791744 @default.
• W2962964955 hasAuthorship W2962964955A5029514013 @default.
• W2962964955 hasAuthorship W2962964955A5075599271 @default.
• W2962964955 hasConcept C106773901 @default.
• W2962964955 hasConcept C115624301 @default.
• W2962964955 hasConcept C121332964 @default.
• W2962964955 hasConcept C139066938 @default.
• W2962964955 hasConcept C147597530 @default.
• W2962964955 hasConcept C152365726 @default.
• W2962964955 hasConcept C155860418 @default.
• W2962964955 hasConcept C161790260 @default.
• W2962964955 hasConcept C178790620 @default.
• W2962964955 hasConcept C185592680 @default.
• W2962964955 hasConcept C192095803 @default.
• W2962964955 hasConcept C502230775 @default.
• W2962964955 hasConcept C54101563 @default.
• W2962964955 hasConcept C54281723 @default.
• W2962964955 hasConcept C62520636 @default.
• W2962964955 hasConcept C71240020 @default.
• W2962964955 hasConcept C8010536 @default.
• W2962964955 hasConceptScore W2962964955C106773901 @default.
• W2962964955 hasConceptScore W2962964955C115624301 @default.
• W2962964955 hasConceptScore W2962964955C121332964 @default.
• W2962964955 hasConceptScore W2962964955C139066938 @default.

• next