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- W2963130548 abstract "Abstract A new FeSe‐based superconductor Li x (C 2 H 8 N 2 ) y Fe 2 Se 2 with Tc =30 K was successfully synthesized by substituting ethylenediamine(en) for ammonia molecules in Li x (NH 3 ) y Fe 2 Se 2 . The XRD pattern indicates that the intercalation compound is an orthorhombic structure with lattice parameters a =3.8517(7)Å, b =3.9188(7)Å, c =21.4862(6)Å at room temperature, which is different from the tetrahedral phase Li x (C 2 H 8 N 2 ) y Fe 2 Se 2 with Tc =45 K synthesized by solvothermal method. Compared with the precursor Li x (NH 3 ) y Fe 2 Se 2 , the Li x (C 2 H 8 N 2 ) y Fe 2 Se 2 underwent a structure transition from tetrahedral to orthorhombic during the amine exchange reaction accompanying by the decrease of Tc , indicating that Tc is influenced by structure." @default.
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- W2963130548 date "2019-07-24" @default.
- W2963130548 modified "2023-10-17" @default.
- W2963130548 title "Preparation of the Orthorhombic Li <sub> <i>x</i> </sub> (C <sub>2</sub> H <sub>8</sub> N <sub>2</sub> ) <sub> <i>y</i> </sub> Fe <sub>2</sub> Se <sub>2</sub> Superconductor by Amine Exchange Method" @default.
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- W2963130548 doi "https://doi.org/10.1002/slct.201901207" @default.
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