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- W2963513007 abstract "A series of Zr4+, Y3+, Fe3+, and Co2+ combinations in solution form and their subsequent potential to yield the desired ZrO2/CoFe2O4 composite that possesses better structural stability at 1300 °C have been presented. The results emphasized the combined effect of heat treatment temperatures and concentration variations in Fe3+/Co2+ to retain tetragonal ZrO2 (t-ZrO2) and CoFe2O4 structures. The incidence of a gradual m- → t-ZrO2 transition alongside the enhanced phase yield of CoFe2O4 is determined. Despite the invariable presence of 8 mol % of Y2O3 in all the investigated systems, the results revealed the inability to establish t-ZrO2 stabilization at 900 and 1100 °C. XPS analysis confirms the oxidation states of iron, yttrium, cobalt, and zirconium in their respective 3+, 3+, 2+, and 4+ in the ZrO2/CoFe2O4 composite. Morphological analysis revealed the presence of distinct grains pertinent to ZrO2 and CoFe2O4 alongside pore free microstructures. The resultant microstructures demonstrated better hardness and Young’s modulus values, and moreover, the gradual increment in the phase content of CoFe2O4 in the composite revealed a corresponding surge in the ferrimagnetic features." @default.
- W2963513007 created "2019-07-30" @default.
- W2963513007 creator A5023438212 @default.
- W2963513007 creator A5042964770 @default.
- W2963513007 date "2019-07-24" @default.
- W2963513007 modified "2023-10-09" @default.
- W2963513007 title "Polymorphism and Phase Transitions in <i>t</i>-ZrO<sub>2</sub>/CoFe<sub>2</sub>O<sub>4</sub> Composite Structures: Impact of Composition and Heat Treatments" @default.
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- W2963513007 doi "https://doi.org/10.1021/acs.cgd.9b00583" @default.
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