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- W2963673202 abstract "6-Aryl-5,6-dihydrodibenzo[c,e][1,2]azaborinines display restricted rotation at the boron–carbon aryl bond, yielding conformational isomers or atropisomers. The stereodynamic processes were monitored by variable-temperature NMR (D-NMR), dynamic enantioselective HPLC (D-HPLC), or kinetic racemization measurements. The absolute configuration of stable atropisomers (compound 1d, ΔG⧧rac = 26.0 kcal·mol–1) was determined by TD-DFT simulation of the electronic circular dichroism (ECD) spectra. The racemization energy of 1d is more than 12 kcal·mol–1 smaller than its isostere 9-(2-methylnaphthalen-1-yl)phenanthrene." @default.
- W2963673202 created "2019-07-30" @default.
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- W2963673202 date "2019-07-19" @default.
- W2963673202 modified "2023-10-18" @default.
- W2963673202 title "Axial Chirality at the Boron–Carbon Bond: Synthesis, Stereodynamic Analysis, and Atropisomeric Resolution of 6-Aryl-5,6-dihydrodibenzo[<i>c,e</i>][1,2]azaborinines" @default.
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- W2963673202 doi "https://doi.org/10.1021/acs.joc.9b01550" @default.
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