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- W2963684922 abstract "Given the specificity of the structure and function of graphene oxide (GO), hybridization with a variety of compounds will further extend its applications. To that end, we examined a new method for introducing a polymer brush onto the GO surface. In this method, GO was surface-modified with 2-((3-((2-bromo-2-methylpropanoyl)oxy)propyl)thio)ethylamine hydrochloride, which is a newly synthesized compound that contains an initiating group for atom transfer radical polymerization (ATRP) and an amino group for reacting with the epoxy groups on the GO surface. The ATRP-initiator-functionalized GO was then used as a substrate for the surface-initiated ATRP of methyl methacrylate (MMA), which produced graft polymers of poly(MMA) (PMMA) with targeted molecular weights and narrow molecular weight distributions; the average graft density was ∼0.06 chains/nm2. Because of their high dispersibilities and structural anisotropies, the PMMA-brush-decorated GOs formed lyotropic liquid crystals in their suspensions. In addition, similar suspensions with relatively high hybrid concentrations exhibited structural color that depended on the concentration." @default.
- W2963684922 created "2019-07-30" @default.
- W2963684922 creator A5001421656 @default.
- W2963684922 creator A5001660488 @default.
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- W2963684922 date "2019-07-25" @default.
- W2963684922 modified "2023-10-17" @default.
- W2963684922 title "Polymer-Brush-Decorated Graphene Oxide: Precision Synthesis and Liquid-Crystal Formation" @default.
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- W2963684922 doi "https://doi.org/10.1021/acs.langmuir.9b01747" @default.
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