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• W2964070671 startingPage "10280" @default.
• W2964070671 abstract "A quadruple perovskite LaMn3Rh4O12 with A′ = Mn and B = 4d transition metal was synthesized at high pressure (8 GPa) and temperature (1423 K) for the first time. Room temperature powder X-ray diffraction indicates that LaMn3Rh4O12 forms in cubic symmetry (Im3̅, a = 7.4997(1) Å). X-ray absorption near-edge spectroscopy shows predominantly Mn3+ and Rh3+ oxidation states. An antiferromagnetic transition at TN ∼ 41 K is corroborated by specific heat measurements. The resistivity measurements indicate a three-dimensional Mott variable-range hopping conduction mechanism between 300 and 160 K." @default.
• W2964070671 created "2019-07-30" @default.
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• W2964070671 date "2019-07-25" @default.
• W2964070671 modified "2023-10-15" @default.
• W2964070671 title "LaMn₃Rh₄O₁₂: An Antiferromagnetic Quadruple Perovskite Synthesized at High Pressure" @default.
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• W2964070671 doi "https://doi.org/10.1021/acs.inorgchem.9b01425" @default.
• W2964070671 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31342741" @default.
• W2964070671 hasPublicationYear "2019" @default.
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