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• W2964213175 abstract "We have investigated the temperature and magnetic field dependence of magnetization, specific heat (Cp), and relative sample length change (ΔL/L0) for understanding the field-induced spin-structural change in quasi-one-dimensional spin chain α-CoV2O6 which undergoes antiferromagnetic (AFM) transition below TN = 15 K. Analysis of Cp(T) shows that an effective S = 1/2 Ising state is realized below 20 K, though the magnetic fluctuations persist well above TN. Cp and the coefficient of linear thermal expansion (α) exhibit strong H dependence in the AFM state. We also observe a huge positive magnetostriction [ΔL(H)/L0] below 20 K which does not show any tendency of saturation up to 9 T. With increasing field, a sharp and symmetric peak emerges below TN in both Cp(T) and α(T) due to field-induced first-order ferrimagnetic/ferromagnetic-paramagnetic transitions. The large value of magnetostriction below TN suggests strong spin–lattice coupling in α-CoV2O6." @default.
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• W2964213175 date "2014-01-13" @default.
• W2964213175 modified "2023-09-26" @default.
• W2964213175 title "Field-Induced Spin-Structural Transition and Giant Magnetostriction in Ising Chain α-CoV₂O₆" @default.
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• W2964213175 doi "https://doi.org/10.1021/jp4069812" @default.
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