FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2964214703> ?p ?o ?g. }

• W2964214703 abstract "Catalytic alkane oxychlorination has recently been demonstrated as attractive for the selective conversion of natural gas into olefins, which are pivotal commodities of the chemical industry. Herein, the oxychlorination of ethane, propane, and butane over metal phosphates (Fe, Mn, and V), europium oxychloride, titanium oxide, and cerium oxide is investigated to assess the role of the carbon number on the reactivity and product distribution. Three categories of catalysts are distinguished: systems showing the highest activity in the oxychlorination of ethane CeO 2 , (VO) 2 P 2 O 7 , propane (EuOCl, FePO 4 , TiO 2 ), or butane (Mn 3 (PO 4 ) 2 ). All catalysts achieve high (70–95%) selectivity toward ethylene in ethane oxychlorination, whereas they favor combustion and cracking pathways in the case of propane and particularly of butane. Furthermore, the catalytic oxidation of alkane and of HCl and alkyl chloride dehydrochlorination is assessed to rationalize the catalytic performance, revealing a linear correlation between the reactivity of the catalysts and the ability of the material to evolve chlorine, which weakens with increasing carbon number. In addition, the olefin selectivity in alkane oxychlorination is found to be driven by the rate of alkyl chloride dehydrochlorination and the propensity toward alkane cracking and combustion over the catalysts, both increasing from ethane to butane." @default.
• W2964214703 created "2019-07-30" @default.
• W2964214703 creator A5007349453 @default.
• W2964214703 creator A5017211660 @default.
• W2964214703 creator A5036481145 @default.
• W2964214703 creator A5059144530 @default.
• W2964214703 date "2019-07-30" @default.
• W2964214703 modified "2023-10-16" @default.
• W2964214703 title "Alkane Functionalization via Catalytic Oxychlorination: Performance as a Function of the Carbon Number" @default.
• W2964214703 cites W1964441532 @default.
• W2964214703 cites W1976705828 @default.
• W2964214703 cites W1996923858 @default.
• W2964214703 cites W1997742620 @default.
• W2964214703 cites W2002283541 @default.
• W2964214703 cites W2011147745 @default.
• W2964214703 cites W2011206098 @default.
• W2964214703 cites W2011520287 @default.
• W2964214703 cites W2019478879 @default.
• W2964214703 cites W2021550094 @default.
• W2964214703 cites W2029837925 @default.
• W2964214703 cites W2054107244 @default.
• W2964214703 cites W2065683180 @default.
• W2964214703 cites W2082947442 @default.
• W2964214703 cites W2087456021 @default.
• W2964214703 cites W2088400298 @default.
• W2964214703 cites W2108812250 @default.
• W2964214703 cites W2121149822 @default.
• W2964214703 cites W2158868670 @default.
• W2964214703 cites W2326125040 @default.
• W2964214703 cites W2552045471 @default.
• W2964214703 cites W2555114778 @default.
• W2964214703 cites W2557521583 @default.
• W2964214703 cites W2571835842 @default.
• W2964214703 cites W2582877518 @default.
• W2964214703 cites W2584215052 @default.
• W2964214703 cites W2744646082 @default.
• W2964214703 cites W2755892564 @default.
• W2964214703 cites W2766797220 @default.
• W2964214703 cites W2768751577 @default.
• W2964214703 cites W2795879216 @default.
• W2964214703 cites W2800638314 @default.
• W2964214703 cites W2909358988 @default.
• W2964214703 cites W2911923304 @default.
• W2964214703 cites W2947452442 @default.
• W2964214703 cites W4229756126 @default.
• W2964214703 cites W4240679575 @default.
• W2964214703 doi "https://doi.org/10.1002/ente.201900622" @default.
• W2964214703 hasPublicationYear "2019" @default.
• W2964214703 type Work @default.
• W2964214703 sameAs 2964214703 @default.
• W2964214703 citedByCount "3" @default.
• W2964214703 countsByYear W29642147032021 @default.
• W2964214703 countsByYear W29642147032023 @default.
• W2964214703 crossrefType "journal-article" @default.
• W2964214703 hasAuthorship W2964214703A5007349453 @default.
• W2964214703 hasAuthorship W2964214703A5017211660 @default.
• W2964214703 hasAuthorship W2964214703A5036481145 @default.
• W2964214703 hasAuthorship W2964214703A5059144530 @default.
• W2964214703 hasConcept C142724271 @default.
• W2964214703 hasConcept C161790260 @default.
• W2964214703 hasConcept C178790620 @default.
• W2964214703 hasConcept C179104552 @default.
• W2964214703 hasConcept C185592680 @default.
• W2964214703 hasConcept C204787440 @default.
• W2964214703 hasConcept C2776345496 @default.
• W2964214703 hasConcept C2776910235 @default.
• W2964214703 hasConcept C2777207669 @default.
• W2964214703 hasConcept C2778717364 @default.
• W2964214703 hasConcept C2781327020 @default.
• W2964214703 hasConcept C51886252 @default.
• W2964214703 hasConcept C71924100 @default.
• W2964214703 hasConceptScore W2964214703C142724271 @default.
• W2964214703 hasConceptScore W2964214703C161790260 @default.
• W2964214703 hasConceptScore W2964214703C178790620 @default.
• W2964214703 hasConceptScore W2964214703C179104552 @default.
• W2964214703 hasConceptScore W2964214703C185592680 @default.
• W2964214703 hasConceptScore W2964214703C204787440 @default.
• W2964214703 hasConceptScore W2964214703C2776345496 @default.
• W2964214703 hasConceptScore W2964214703C2776910235 @default.
• W2964214703 hasConceptScore W2964214703C2777207669 @default.
• W2964214703 hasConceptScore W2964214703C2778717364 @default.
• W2964214703 hasConceptScore W2964214703C2781327020 @default.
• W2964214703 hasConceptScore W2964214703C51886252 @default.
• W2964214703 hasConceptScore W2964214703C71924100 @default.
• W2964214703 hasIssue "8" @default.
• W2964214703 hasLocation W29642147031 @default.
• W2964214703 hasOpenAccess W2964214703 @default.
• W2964214703 hasPrimaryLocation W29642147031 @default.
• W2964214703 hasRelatedWork W1966373146 @default.
• W2964214703 hasRelatedWork W2004954297 @default.
• W2964214703 hasRelatedWork W2016461098 @default.
• W2964214703 hasRelatedWork W2036822140 @default.
• W2964214703 hasRelatedWork W2065441507 @default.
• W2964214703 hasRelatedWork W2077773780 @default.
• W2964214703 hasRelatedWork W2080173673 @default.
• W2964214703 hasRelatedWork W2133025452 @default.
• W2964214703 hasRelatedWork W4236421167 @default.
• W2964214703 hasRelatedWork W4253015343 @default.
• W2964214703 hasVolume "8" @default.
• W2964214703 isParatext "false" @default.

• next