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- W2964334015 abstract "The aim of this study was to gain deeper insight into the factors determining the activity and selectivity of mono- (Au, Cu) and bimetallic (AuCu) catalysts supported on Nb2O5 in methanol photooxidation. For this purpose, the prepared catalysts were characterized with the use of XRD, nitrogen sorption, ICP-OES, UV–vis, XPS, TEM and FTIR spectroscopy. Photocatalytic activity of materials was evaluated with the use of operando-IR system under UV and visible light irradiation. It was demonstrated that under visible light irradiation, the decoration of the niobia with bimetallic nanoparticles of gold and copper led to a synergic enhancement of the photocatalyst performance relative that of monometallic and non-doped niobia photocatalysts, tested under the same reaction conditions. It was also demonstrated that selectivity over the bimetallic gold-copper/Nb2O5 catalyst was strongly affected by the nature of light source: visible light promoted a total oxidation versus a partial oxidation of methanol under UV light." @default.
- W2964334015 created "2019-07-30" @default.
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- W2964334015 creator A5081422662 @default.
- W2964334015 creator A5082286443 @default.
- W2964334015 date "2019-12-01" @default.
- W2964334015 modified "2023-10-17" @default.
- W2964334015 title "Insight into methanol photooxidation over mono- (Au, Cu) and bimetallic (AuCu) catalysts supported on niobium pentoxide — An operando-IR study" @default.
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- W2964334015 doi "https://doi.org/10.1016/j.apcatb.2019.117978" @default.
- W2964334015 hasPublicationYear "2019" @default.
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