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• W2964445319 abstract "Rechargeable Mg batteries are attractive candidates for large‐scale energy storage batteries with high safety due to the low‐cost and non‐dendritic metallic Mg anode. However, exploring high‐performance cathode materials is blocking their development. Herein, a high‐rate rechargeable Mg battery is established with a AgCl cathode, delivering a high reversible capacity of 70.3 mAh g −1 at 100 mA g −1 , an outstanding rate capability of 32.6 mAh g −1 at 1000 mA g −1 , and a superior long‐term cyclability over 500 cycles. Further investigation of the mechanism demonstrates that a conversion reaction takes place between AgCl and metallic Ag 0 for the cathode. The solid‐state Mg 2+ diffusion coefficient is as high as 8.1 × 10 −11 cm 2 s −1 , which would be the reason for the high rate capability. The current study reveals significant insights to select promising Mg‐storage conversion cathodes by a combination of soft anions and soft transition‐metal cations." @default.
• W2964445319 created "2019-08-13" @default.
• W2964445319 creator A5007929157 @default.
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• W2964445319 date "2019-06-18" @default.
• W2964445319 modified "2023-09-30" @default.
• W2964445319 title "A High‐Rate Rechargeable Mg Battery Based on AgCl Conversion Cathode with Fast Solid‐State Mg²⁺Diffusion Kinetics" @default.
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• W2964445319 doi "https://doi.org/10.1002/ente.201900454" @default.
• W2964445319 hasPublicationYear "2019" @default.
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