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• W2964498325 endingPage "6518" @default.
• W2964498325 startingPage "6513" @default.
• W2964498325 abstract "A new family of sulfinamide/sulfoxide derivatives was synthesized as chiral bidentate ligands by stereoselective additions of methylsulfinyl carbanions to N-tert-butylsulfinylimines. The new ligands, with C1, pseudo-meso, and pseudo-C2 symmetries, were successfully assayed in Rh-catalyzed additions of arylboronic acids to activated ketones. The sterically dissymmetric C1 ligand (RS,SC,RS)-N-[1-(phenylsulfinyl)-3-methylbut-2-yl] tert-butylsulfinamide turned out to be the optimal one, allowing the 1,4-additions of diverse arylboronic acids, on different α,β-unsaturated cyclic ketones with high chemical yields and enantioselectivities up to >99% ee." @default.
• W2964498325 created "2019-08-13" @default.
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• W2964498325 date "2019-07-31" @default.
• W2964498325 modified "2023-10-01" @default.
• W2964498325 title "Steric Tuning of Sulfinamide/Sulfoxides as Chiral Ligands with <i>C</i>₁, Pseudo-<i>meso</i>, and Pseudo-<i>C</i>₂ Symmetries: Application in Rhodium(I)-Mediated Arylation" @default.
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• W2964498325 doi "https://doi.org/10.1021/acs.orglett.9b02405" @default.
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• W2964498325 hasPublicationYear "2019" @default.
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