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• W2964995147 abstract "As Mo3Se3- chain nanowires have dimensions comparable to those of natural hydrogel chains (molecular-level diameters of ∼0.6 nm and lengths of several micrometers) and excellent mechanical strength and flexibility, they have large potential to reinforce hydrogels and improve their mechanical properties. When a Mo3Se3--chain-nanowire-gelatin composite hydrogel is prepared simply by mixing Mo3Se3- nanowires with gelatin, phase separation of the Mo3Se3- nanowires from the gelatin matrix occurs in the micronetwork, providing only small improvements in their mechanical properties. In contrast, when the surface of the Mo3Se3- nanowire is wrapped with the gelatin polymer, the chemical compatibility of the Mo3Se3- nanowire with the gelatin matrix is significantly improved, which enables the fabrication of a phase-separation-free Mo3Se3--reinforced gelatin hydrogel. The composite gelatin hydrogel exhibits significantly improved mechanical properties, including a tensile strength of 27.6 kPa, fracture toughness of 26.9 kJ/m3, and elastic modulus of 54.8 kPa, which are 367%, 868%, and 378% higher than those of the pure gelatin hydrogel, respectively. Furthermore, the amount of Mo3Se3- nanowires added in the composite hydrogel is as low as 0.01 wt %. The improvements in the mechanical properties are significantly larger than those for other reported composite hydrogels reinforced with one-dimensional materials." @default.
• W2964995147 created "2019-08-13" @default.
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• W2964995147 date "2019-08-01" @default.
• W2964995147 modified "2023-10-18" @default.
• W2964995147 title "Exceptional Mechanical Properties of Phase-Separation-Free Mo₃Se₃^–-Chain-Reinforced Hydrogel Prepared by Polymer Wrapping Process" @default.
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• W2964995147 doi "https://doi.org/10.1021/acs.nanolett.9b02343" @default.
• W2964995147 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31369273" @default.
• W2964995147 hasPublicationYear "2019" @default.
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