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- W2965114810 abstract "Asymmetric catalysis by using novel chiral O,O'-chelated 4,4'-biphenol cyclometalated oxazoline gold(III) complexes has been developed. A high yield (≤89%) and a high enantioselectivity (≤90% ee) were achieved in asymmetric carboalkoxylation of alkynes. Enantioselectivity could be significantly improved from 19% to 90% ee by increasing the steric size of the substituent on the chiral oxazoline ligand. Catalytically active AuIII species and the origin of chiral induction are proposed." @default.
- W2965114810 created "2019-08-13" @default.
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- W2965114810 date "2019-08-06" @default.
- W2965114810 modified "2023-10-14" @default.
- W2965114810 title "Chiral Cyclometalated Oxazoline Gold(III) Complex-Catalyzed Asymmetric Carboalkoxylation of Alkynes" @default.
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- W2965114810 doi "https://doi.org/10.1021/acs.orglett.9b02171" @default.
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