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- W2965222898 abstract "A series of five iron and aluminum complexes bearing {ONSO} imine thiobis(phenolate) ligands have been prepared and applied to the ring-opening polymerization (ROP) of rac-lactide. Fe(1)Cl produced polylactide with a very strong isotactic bias (Pm = 0.79–0.89) and well-defined melting temperatures (Tm = 154–181 °C). The polymers have been characterized by a combination of 1H{1H} NMR, 13C{1H} NMR, gel permeation chromatography, thermogravimetric analysis, differential scanning calorimetry, and powder X-ray diffraction. Fe(1)Cl has also been shown to activate CO2, at atmospheric pressure and concentrations, to form a carbonato-bridged dimer. Fe(2–5)Cl and Al(1–5)Me were also active for lactide ROP demonstrating good-molecular-weight control (Đ = 1.04–1.12) and moderate isotactic preference (Pm = 0.56–0.72), with polymerization outcome correlating with ligand substituents." @default.
- W2965222898 created "2019-08-13" @default.
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- W2965222898 date "2019-07-31" @default.
- W2965222898 modified "2023-10-18" @default.
- W2965222898 title "Tuning the Thiolen: Al(III) and Fe(III) Thiolen Complexes for the Isoselective ROP of <i>rac</i>-Lactide" @default.
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- W2965222898 doi "https://doi.org/10.1021/acs.macromol.9b01205" @default.
- W2965222898 hasPublicationYear "2019" @default.
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