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- W2965400790 abstract "Stereoselective synthesis of deoxyglycosides has been achieved from benchtop stable and easily synthesizable deoxy-phenylpropiolate glycosides (D-PPGs) using gold(III) salt as catalyst under external additive-free conditions. Under a simple catalytic system, D-PPGs reacted with a variety of sugar and non-sugar acceptors to produce majorly α-stereoselective O/N-deoxyglycosides in good to excellent yields and regenerate easily separable and reusable phenylpropiolic acid. Deoxy-PPGs containing armed and disarmed groups survived well under the optimized reaction conditions. In addition, the orthogonal nature of D-PPGs was showcased, and 1,1'-linked trehalose-type sugar was also synthesized." @default.
- W2965400790 created "2019-08-13" @default.
- W2965400790 creator A5012196047 @default.
- W2965400790 creator A5082687363 @default.
- W2965400790 date "2019-08-13" @default.
- W2965400790 modified "2023-10-01" @default.
- W2965400790 title "Additive‐Free Gold(III)‐Catalyzed Stereoselective Synthesis of 2‐Deoxyglycosides Using Phenylpropiolate Glycosides as Donors" @default.
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- W2965400790 doi "https://doi.org/10.1002/asia.201900888" @default.
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