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- W2965461159 abstract "A chiral carthamin model (3 S ,3′ S )‐1‐[5‐acetyl‐2,6‐diketo‐3‐ C ‐β‐ d ‐glucopyranosylcyclohex‐4‐enylidene]‐1′‐[5′‐acetyl‐3′‐ C ‐β‐ d ‐glucopyranosyl‐2′,3′,4′‐trihydroxy‐6′‐oxocyclohexa‐1′,4′‐dienyl]methane, in which two cinnamoyl groups were replaced by an acetyl group, was synthesized by the dimerization of ( S )‐2‐acetyl‐4‐ C ‐(per‐ O ‐acetyl‐β‐ d ‐glucopyranosyl)cyclohexadienone with glyoxylic acid, followed by peroxidase‐catalyzed oxidative decarboxylation and de‐ O ‐acetylation, or de‐ O ‐acetylation and peroxidase‐catalyzed oxidative decarboxylation. The corresponding total yields were 12.5% or 17.1% from 3‐ C ‐(per‐ O ‐acetyl‐β‐ d ‐glucopyranosyl)phloroacetophenone, and the reaction pathway was identical to the biosynthetic pathway." @default.
- W2965461159 created "2019-08-13" @default.
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- W2965461159 date "2019-07-29" @default.
- W2965461159 modified "2023-09-26" @default.
- W2965461159 title "Synthetic Study of Carthamin: Biomimetic Synthesis of Carthamin Model via Peroxidase‐Catalyzed Oxidative Decarboxylation of Its Precursor Model" @default.
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- W2965461159 doi "https://doi.org/10.1002/jhet.3633" @default.
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