Matches in SemOpenAlex for { <https://semopenalex.org/work/W2965610870> ?p ?o ?g. }
- W2965610870 endingPage "6173" @default.
- W2965610870 startingPage "6163" @default.
- W2965610870 abstract "While a large number of terpolymers have been developed for polymer solar cells, very few studies have directly focused on the rational selection of the third component to balance the miscibility and crystallinity for forming the desired morphology, and universal terpolymer strategies for preparing different donor/acceptor systems are lacking. Herein, we employ a new strategy involving the integration of benzodithiophene (BDT) and thieno[2,3-f]benzofuran (TBF) segments to construct a series of terpolymer donors, and a profound influence on the crystallinity and miscibility of the blend films as well as on the ultimate device performance is observed. Incorporating highly crystalline TBF segments into a low-crystalline BDT-based alternating copolymer can not only increase the order of the microstructure, conserve the favorable face-on orientation, and promote the formation of proper phase-separation features but also generate high exciton dissociation and suppress charge recombination. This strategy was successfully applied in the reported J52 system and provided a remarkable 2-fold boost in performance. Finally, competitive power conversion efficiencies of 11.9, 12.4, and 12.2% accompanied by high fill factors of 73, 71, and 76% were recorded for TBFCl50-FTAZ/ITIC-, TBFCl50-BDD/ITIC-, and TBFCl50-BDD/IDIC-C4Ph-based devices, respectively, via the above terpolymer strategy. Thus, our discovery provides a promising and innovative method for finely controlling the microstructure of heterojunctions for designing high-performance terpolymers." @default.
- W2965610870 created "2019-08-13" @default.
- W2965610870 creator A5010940533 @default.
- W2965610870 creator A5013913480 @default.
- W2965610870 creator A5015065738 @default.
- W2965610870 creator A5034427968 @default.
- W2965610870 creator A5079600746 @default.
- W2965610870 creator A5083377250 @default.
- W2965610870 creator A5083586036 @default.
- W2965610870 creator A5083988411 @default.
- W2965610870 creator A5091527569 @default.
- W2965610870 date "2019-07-25" @default.
- W2965610870 modified "2023-10-17" @default.
- W2965610870 title "Terpolymer Strategy toward High-Efficiency Polymer Solar Cells: Integrating Symmetric Benzodithiophene and Asymmetrical Thieno[2,3-<i>f</i>]benzofuran Segments" @default.
- W2965610870 cites W1760836962 @default.
- W2965610870 cites W1922922125 @default.
- W2965610870 cites W1981934547 @default.
- W2965610870 cites W1988567331 @default.
- W2965610870 cites W1995686102 @default.
- W2965610870 cites W2011184332 @default.
- W2965610870 cites W2018094686 @default.
- W2965610870 cites W2046035451 @default.
- W2965610870 cites W2046143366 @default.
- W2965610870 cites W2047567501 @default.
- W2965610870 cites W2052504022 @default.
- W2965610870 cites W2059075015 @default.
- W2965610870 cites W2068839774 @default.
- W2965610870 cites W2075672118 @default.
- W2965610870 cites W2081835379 @default.
- W2965610870 cites W2082019533 @default.
- W2965610870 cites W2092024458 @default.
- W2965610870 cites W2096320304 @default.
- W2965610870 cites W2118125318 @default.
- W2965610870 cites W2139409061 @default.
- W2965610870 cites W2148176976 @default.
- W2965610870 cites W2223208841 @default.
- W2965610870 cites W2276511412 @default.
- W2965610870 cites W2305124007 @default.
- W2965610870 cites W2307492705 @default.
- W2965610870 cites W2310469160 @default.
- W2965610870 cites W2324978604 @default.
- W2965610870 cites W2499946727 @default.
- W2965610870 cites W2516890670 @default.
- W2965610870 cites W2541201569 @default.
- W2965610870 cites W2545154541 @default.
- W2965610870 cites W2559686099 @default.
- W2965610870 cites W2570753647 @default.
- W2965610870 cites W2598355492 @default.
- W2965610870 cites W2610337915 @default.
- W2965610870 cites W2725833068 @default.
- W2965610870 cites W2729522413 @default.
- W2965610870 cites W2739185928 @default.
- W2965610870 cites W2741591558 @default.
- W2965610870 cites W2747791724 @default.
- W2965610870 cites W2752566573 @default.
- W2965610870 cites W2765775203 @default.
- W2965610870 cites W2768838352 @default.
- W2965610870 cites W2768918326 @default.
- W2965610870 cites W2769988492 @default.
- W2965610870 cites W2773599771 @default.
- W2965610870 cites W2782786935 @default.
- W2965610870 cites W2789761381 @default.
- W2965610870 cites W2789787743 @default.
- W2965610870 cites W2792783390 @default.
- W2965610870 cites W2793763369 @default.
- W2965610870 cites W2801041974 @default.
- W2965610870 cites W2803016063 @default.
- W2965610870 cites W2805894358 @default.
- W2965610870 cites W2811271967 @default.
- W2965610870 cites W2890016046 @default.
- W2965610870 cites W2890335940 @default.
- W2965610870 cites W2890928012 @default.
- W2965610870 cites W2893389901 @default.
- W2965610870 cites W2896806471 @default.
- W2965610870 cites W2898267584 @default.
- W2965610870 cites W2899167418 @default.
- W2965610870 cites W2901775789 @default.
- W2965610870 cites W2902398324 @default.
- W2965610870 cites W2902624183 @default.
- W2965610870 cites W2902875556 @default.
- W2965610870 cites W2909990379 @default.
- W2965610870 cites W2910551123 @default.
- W2965610870 cites W2912017373 @default.
- W2965610870 cites W2912638677 @default.
- W2965610870 cites W2913877418 @default.
- W2965610870 cites W2918054062 @default.
- W2965610870 cites W2942435343 @default.
- W2965610870 cites W2948430407 @default.
- W2965610870 cites W2948673221 @default.
- W2965610870 cites W2948869268 @default.
- W2965610870 cites W4211160986 @default.
- W2965610870 doi "https://doi.org/10.1021/acs.chemmater.9b01957" @default.
- W2965610870 hasPublicationYear "2019" @default.
- W2965610870 type Work @default.
- W2965610870 sameAs 2965610870 @default.
- W2965610870 citedByCount "46" @default.
- W2965610870 countsByYear W29656108702019 @default.
- W2965610870 countsByYear W29656108702020 @default.