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• W2965617130 startingPage "11146" @default.
• W2965617130 abstract "Constructing exquisite and intricate molecular architectures is always the pursuit of chemists. In this report, the propeller-shaped trefoil structures S1 and S2 were successfully prepared by the stepwise self-assembly of predesigned tripodal metal–organic ligands, which consist of bis(terpyridine)s-Ru2+-tris(terpyridine)s connectivities for the following complexation with Fe2+. The complexes can be described as racemic spiral assemblies with three-fold spiralism. These unique discrete metal–organic architectures were fully characterized by 1H NMR, 2D NMR spectroscopy (COSY and NOESY), diffusion-ordered NMR spectroscopy (DOSY), ESI-MS, TWIM-MS, and TEM, and their photophysical and electrochemical properties were also investigated. Further, hybrid trefoiled structure [Fe3L1L2] was detected by taking advantage of the flexibility of metal–organic ligands." @default.
• W2965617130 created "2019-08-13" @default.
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• W2965617130 date "2019-07-30" @default.
• W2965617130 modified "2023-09-25" @default.
• W2965617130 title "Trefoiled Propeller-Shaped Spiral Terpyridyl Metal–Organic Architectures" @default.
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• W2965617130 doi "https://doi.org/10.1021/acs.inorgchem.9b01701" @default.
• W2965617130 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31361129" @default.
• W2965617130 hasPublicationYear "2019" @default.
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