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• W2965670261 abstract "Cocatalysts play a significant role in accelerating the catalytic reactions of semiconductor photocatalyst. In particular, a semiconductor assembled with dual cocatalysts, i.e., reduction and oxidation cocatalysts, can obviously enhance the photocatalytic performance because of the synergistic effect of fast consumption of photogenerated electrons and holes simultaneously. However, in most cases, noble metal cocatalysts are employed, which tremendously increases the cost of the photocatalysts and restricts their large-scale applications. Herein, on the platform of one-dimensional (1D) CdS nanowires, we have utilized the earth-abundant dual cocatalysts, MoS2 and cobalt phosphate (Co-Pi), to construct the CdS@MoS2@Co-Pi (CMC) core-shell hybrid photocatalysts. In this dual-cocatalyst system, Co-Pi is in a position to expedite the migration of holes from CdS, while MoS2 acts as an electron transporter as well as active sites to accelerate the surface water reduction reaction. Taking the advantages of the dual-cocatalyst system, the prepared CMC hybrid shows an obvious enhancement of both the photoactivity and photostability toward hydrogen production compared with bare 1D CdS nanowires and binary hybrids (CdS@MoS2 and CdS@Co-Pi). This work highlights the promising prospects for rational utilization of earth-abundant dual cocatalysts to design low-cost and efficient hybrids toward boosting photoredox catalysis." @default.
• W2965670261 created "2019-08-13" @default.
• W2965670261 creator A5026347224 @default.
• W2965670261 creator A5066033097 @default.
• W2965670261 creator A5086250289 @default.
• W2965670261 creator A5088285649 @default.
• W2965670261 date "2019-07-31" @default.
• W2965670261 modified "2023-10-17" @default.
• W2965670261 title "Earth-Abundant MoS₂ and Cobalt Phosphate Dual Cocatalysts on 1D CdS Nanowires for Boosting Photocatalytic Hydrogen Production" @default.
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• W2965670261 doi "https://doi.org/10.1021/acs.langmuir.9b01409" @default.
• W2965670261 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31365263" @default.
• W2965670261 hasPublicationYear "2019" @default.
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