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- W2966022386 abstract "Imidazolium-based gemini surfactants were attracted extensive attention in recent years with varied benefits such as good biodegradability, low irritant and little toxicity. In this paper, a series of imidazolium-based gemini surfactants with a four-methylene spacer and long hydrophobic chains ([Cn-4-Cnim]Br2, n = 12, 14, 16) were fabricated for modification of vermiculite. The primary characterization of organo-vermiculites (OVts) like Infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TG-DTG), scanning electron microscope (SEM), wettability and Elemental Analysis were carried out. The resultant OVts were used to remove dimethyl phthalate (DMP) from aqueous solution, particularly C14-4-C14im-Vt showed the most promising adsorbability (274.4 mg g−1) which is efficient comparing with other adsorbents. The adsorption processes turned out to follow the pseudo-second-order and Langmuir isotherm. Furthermore, the wettabilities of OVts followed the order: C14-4-C14im-Vt > C12-4-C12im-Vt > C16-4-C16im-Vt, which appeared in a positive correlation with the adsorption capacities. Draw a conclusion the sorption occurred primarily via hydrophobic interaction and π–π interaction between OVts and DMP. C14-4-C14im-Vt could be favorably reproduced by ethanol at least for five cycles. It provides some new thoughts for the possibility of design and synthesis of OVts as high-efficiency adsorbents." @default.
- W2966022386 created "2019-08-13" @default.
- W2966022386 creator A5005877937 @default.
- W2966022386 creator A5034849894 @default.
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- W2966022386 creator A5080183359 @default.
- W2966022386 date "2019-11-01" @default.
- W2966022386 modified "2023-10-18" @default.
- W2966022386 title "The efficient removal of dimethyl phthalate by three organo-vermiculites with imidazolium-based gemini surfactants in aqueous media" @default.
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- W2966022386 doi "https://doi.org/10.1016/j.colsurfa.2019.123726" @default.
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